異核配合物K2[Co(Dipc)2]·7H2O的合成、性質(zhì)、結(jié)構(gòu)和熱分解動(dòng)力學(xué)研究

A heteronuclear compound, K2 [ Co (Dipc) 2 ] @ 7H2O (Dipc = pyridine-2, 6-dicarboxylic acid) has been synthesized and characterized by IR, elemental analysis, and X-ray diffraction. Crystal data: orthorhombic system withspace group Pnna and unite cell parameters: a =2. 0645(3) nm, b = 1. 3484(2) nm, c =0. 8204(1) nm; V=2.2838(6) nm3, Z=4, Dca1d=1.726g@cm-3, μ=1.193mm-1, F(000)=1212, Gof=1.045, △ρ=339～ -348 e @ nm-3, the final R is 0. 0295. In the molecule of the complex, Co (Ⅱ) ion is six-coordinate to form a dis-torted octahedron. The N atom and the carboxyl group of pyridine-2, 6-dicarboxylic acid are coordinated with thecentral ions. One of the carboxyl groups of the pyridine-2, 6-dicarboxylic acid connect K (Ⅰ) and Co (Ⅱ). The com-pound possesses approximate C2 symmetry. The compounds form a three-dimensional network of infinite lengthconnection with crystal waters, potassium ions and hydrogen bonds. The result of kinetics of thermal decompositionindicated that the compound decomposition takes place in two steps.

作 者： 張淑華 蔣毅民 肖瑜   作者單位： 張淑華(桂林工學(xué)院材料與化學(xué)工程系,桂林,541004)

蔣毅民(廣西師范大學(xué)化學(xué)化工學(xué)院,桂林,541004)

肖瑜(桂林工學(xué)院資源與環(huán)境工程系,桂林,541004) 

刊 名： 無機(jī)化學(xué)學(xué)報(bào)  ISTIC SCI PKU 英文刊名： CHINESE JOURNAL OF INORGANIC CHEMISTRY  年，卷(期)： 2003 19(12)  分類號(hào)： O614.113 O614.81+2  關(guān)鍵詞： 吡啶-2,6-二甲酸   異核配合物   晶體結(jié)構(gòu)   熱分解動(dòng)力學(xué)   pyridine-2,6-dicarboxylic acid heteronuclear compound crystal structure kinetics of thermal decomposition  

【異核配合物K2[Co(Dipc)2]·7H2O的合成、性質(zhì)、結(jié)構(gòu)和熱分解】相關(guān)文章：

Co(Ⅱ)和Ni(Ⅱ)2-乙酰吡啶乙醇胺配合物合成與結(jié)構(gòu)04-26

兩種Cr(Ⅲ)配合物的合成、結(jié)構(gòu)和光物理性質(zhì)04-26

新型環(huán)狀金屬Pt(Ⅱ)配合物:合成、晶體結(jié)構(gòu)及光譜性質(zhì)04-27

銅(Ⅱ)配合物[Cu(pydc)(H2O)2]2合成、結(jié)構(gòu)和量子化學(xué)的研究04-26

氯代苯基卟啉-氨基酸及鋅配合物的合成和光譜性質(zhì)04-27

配位聚合物Cu(phth)2(H2O)2的合成、晶體結(jié)構(gòu)與熱重、熒光性質(zhì)04-26

配合物[Mn(phen)(H2O)4]·SO4·2H2O的合成、晶體結(jié)構(gòu)和表征04-26

含偶磷氮烷配體的三核釕羰基簇合物的合成和晶體結(jié)構(gòu)04-26

合成氨副產(chǎn)CO2氣的回收與利用04-25

熔融法合成甘氨酸鋅配合物及表征04-27